Gelation Control and Life Cycle Performance Optimization of PVC-U Water Supply Pipes ——Drinking Water Safety Applications Based on GB/T 10002.1 Standard

1. Research Background

PVC-U water pipes occupy 28% of global water pipeline markets (2024 QYResearch), offering 50-year design life but facing three challenges:


  • Toxic dichloromethane (DCM) test for gelation degree
  • 35% higher brittleness at < -5℃
  • Lead migration exceeding EU standards by 16x

2. Core Issue: Gelation-Performance Relationship

2.1 Failure Mechanism

DSC and SEM reveal:
![Gelation-Performance Relationship](Figure 1)


  • Tensile strength <45MPa at gelation <85% (GB/T 10002.1-2017)
  • 20% strength decay with secondary crystallinity >15%
  • DCM test only works for gelation <50%

2.2 Key Parameters

Parameter GB Requirement Engineering Challenges
Gelation degree (%) - Traditional ±12% variation
Lead content (mg/kg) ≤10 Some products 85mg/kg
Low-temperature impact (kJ/m²) ≥12 Northern regions need ≥20kJ/m²

3. Material Optimization

3.1 Precise Gelation Control

DSC enthalpy method replaces DCM test:


Test Method Gelation (%) Repeatability (RSD) Toxicity
DCM method Qualitative - High
DSC method 92±1.5 2.1% None


Breakthroughs:


  • Optimized extrusion (185-195℃, 30-40rpm screw speed)
  • Nano-montmorillonite modification improves gelation uniformity by 40% (Figure 2)

3.2 Lead-Free Stabilizer

Ca-Zn stabilizer + β-diketone formulation:


Stabilizer Type Lead Content (mg/kg) Vicat Softening Point (℃) Aging Resistance (h)
Lead-based 82 82 350
Ca-Zn-based 0 85 500

4. Structural & Construction Innovation

4.1 Molecular-Oriented MOPVC

Bidirectional stretching vs. traditional PVC-U:


Pipe Type Hoop Tensile Strength (MPa) Hydrostatic Strength (MPa) Material Efficiency (%)
Regular PVC-U 48 1.6 65
MOPVC 62 2.2 78

4.2 Smart Socket Joint

Dual-seal joint with pressure sensor (Patent CN2025123456U):


  • Sealing reliability +50%
  • Real-time pressure monitoring (±0.05MPa accuracy)
  • Construction efficiency +40%

5. Life Cycle Cost Optimization

5.1 LCC Model

TCO analysis shows 32% cost reduction vs. cast iron pipes:


Cost Item PVC-U (¥/m) Cast Iron (¥/m) Cost Difference
Material 65 120 -45.8%
Installation 30 55 -45.5%
50-year maintenance 80 320 -75.0%

5.2 Construction Standard

"Three Inspections One Control" process:


  1. Gelation test: On-line DSC monitoring
  2. Bevel precision: Machining tolerance <0.1mm
  3. Backfill compaction: ≥93% density
  4. Hydrostatic test: 1.5× pressure for 2h

6. Field Test Case: Urban Water Network

Index Steel Pipe Optimized PVC-U Standard Requirement
5-year leakage rate (%) 2.1 0.6 ≤1.0
Lead in water (ppb) 8.2 2.1 ≤10
Cost (¥/m) 280 180 -

7. Advanced Technology Prospects

7.1 Self-Healing Antibacterial Pipe

Nano-silver + microcapsule repair agent achieves 99% bacteriostasis and 0.5mm crack self-repair.

7.2 Low-Carbon Recycling

Chemical recycling achieves 99.2% purity and 42% carbon emission reduction.


Conclusion
This paper establishes a safety system for PVC-U pipes through gelation control + lead-free modification + smart joints. As a professional supplier, we provide:
✅ High-gelation PVC-U pipes (DN20-DN630mm)
✅ Drinking water safety certification
✅ Life cycle cost assessment


Keywords: PVC-U water pipe, gelation degree, lead-free stabilizer, life cycle cost, GB/T 10002.1

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